Kenny Wayne Shepherd feat. B.B. King
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Kenny Wayne Shepherd with B.B. King footage is from Kenny's CD/DVD "10 Days Out: Blues from the Backroads".
It documents the birthplace of the Blues, and was recorded without any fancy tricks or editing, just real artists recording the Blues as it has always been played.
The song is "The Thrill is Gone", written by Roy Hawkins and Rick Darnell in 1951 which later became a major hit for B.B. King.